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Class 12 › Chemistry › Chemical Kinetics
CBSE2026Class Class 12 · Chemistry3 Marks · Short✅ Verified
For the first order thermal decomposition reaction, following data was obtained :
$$C_2H_5Cl(g) \longrightarrow C_2H_4(g) + HCl(g)$$
| S. No. | Time (s) | Total Pressure (atm) |
| --- | --- | --- |
| 1 | 0 | 0.30 |
| 2 | 30 | 0.50 |
Step 1 - Set up a pressure table.
$$C_2H_5Cl(g) \longrightarrow C_2H_4(g) + HCl(g)$$
At $t = 0$ : $\quad p_0 = 0.30$ atm, $\quad 0$, $\quad 0$
At $t = t$ : $\quad (p_0 - x)$, $\quad x$, $\quad x$
where $x$ = pressure of $C_2H_5Cl$ that has decomposed.
Step 2 - Relate $x$ to the total pressure.
$$p_{total} = (p_0 - x) + x + x = p_0 + x$$
At $t = 30$ s, $p_{total} = 0.50$ atm and $p_0 = 0.30$ atm:
$$0.50 = 0.30 + x$$
$$x = 0.20\ \text{atm}$$
Step 3 - Find the pressure of the reactant left at $t = 30$ s.
$$p_A = p_0 - x = 0.30 - 0.20 = 0.10\ \text{atm}$$
Step 4 - Apply the first order integrated rate equation.
For a gaseous first order reaction, partial pressures may be used in place of
concentrations:
$$k = \frac{2.303}{t}\log\frac{p_0}{p_A}$$